hfa-2039 (RON/MON improvers)
® WRT bvMATERIAL SAFETY DATASHEET
Revision: 2
Revision date: September 2004
1. IDENTIFICATION OF SUBSTANCE OR PREPARATION
preparation details:
- name of preparation: HFA 2039
2. COMPOSITION/DATA ON COMPONENTS
chemical characteristics ( preparation )
- description: Ferrocene ( dicyclopentadienyliron ) in high aromatic hydro-carbon solvent.
hazardous identification:
| substance name | Cas-No. | EU-No. | R-phrase | symbol | contents(mass%) |
|---|---|---|---|---|---|
| Ferrocene | 102-54-5 | 11-22-51/53 | F, Xn, N | >10 | |
| Toluene | 108-883 | R-11-Xn R20 |
<90 |
3. POSSIBLE RISKS
Possible risks for man and environment:
Harmful; may cause lung damage. Prevent material from reaching ground, water sewage systems, holes and cellars. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
4. FIRST AID MEASURES
- general information: Pay attention to the general handling instructions of chemicals
- after inhalation: Supply fresh air
- after skin contact: Wash with water and soap
- after eye contact: Rinse opened eye for several minutes under running water. Get medical attention
- after swallowing: In case of persistent cases call a doctor. Do not drink. Avoid vomiting
- special information for doctors: -
5. FIRE FIGHTING MEASURES
- suitable extinguishing agents: Foam, CO2, extinguishing powder
- unsuitable extinguishing agents: Water jet
- protective equipment: No special measures required
6. ACCIDENTAL RELEASE MEASURES
- person-related safety precautions: Keep unprotected persons away
- measures of environmental protection: Prevent material from reaching sewage systems, holes and cellars
- measures for cleaning/collecting: Absorb with liquid-binding materials
- special information: -
7. HANDLING AND STORAGE
Handling:
- information for safe handling
- Do not breath vapour ( S23 )
- Avoid contact with skin and eyes
- Use only well ventilated areas ( S51 )
- When using, do not eat, drink or smoke ( S20/21 )
- Keep away from heat and sources of ignition
- Take precautionary measures against static discharges ( S33 )
Information about protection against explosions and fire: Keep ignition sources away. Do not smoke.
Storage:
- Storage requirements to be met by storerooms and containers: Observe official regulations on storing packaging and containers.
- information about storage in one common storage facility: -
- further information about storage conditions: Keep container tightly sealed.
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
additional information about design of technical systems: -
components with critical values that require monitoring at the workplace:
CAS-No. substance name type value unit
additional information: -
Personal protective equipment:
- general protective and hygienic measures: wash hands during breaks and at the end of the work. Change soiled clothes immediately
- breathing equipment: -
- protection of hands: gloves, mineral oil resistant
- protection of eyes: goggles
9. PHYSICAL AND CHEMICAL PROPERTIES
appearance:
- form: liquid
- colour: red-brown
- odour: aromatic
physical properties:
- boiling point / boiling range: 170-290 C DIN 51 751
- melting point / melting range: <-30 C
- flashpoint: 4 C DIN 51 758
- ignition temperature: >500 C DIN 51 794
- self ignition: no
- explosion limits: lower: 1,0 upper: 7,0 Vol%
- vapour pressure (15 C): 2,9 kPa DIN 51 640
- density (15 C): 0,9073 g/cm3 DIN 51 757
- solubility in water (15 C ): unsoluble g/l
- pH-value: -
- viscosity (15 C): 0,7987 mm2/s DIN 53 015
10. STABILITY AND REACTIVITY
- conditions to be avoided: under normal conditions undecomposable
- substances to be avoided: strong oxidizing agents
- dangerous substances of decomposition: CO, CO2
- additional information: -
11. TOXICOLOGICAL INFORMATION
- acute toxicity
- LD/C50 values that are relevant for classification:
- LD50 (oral,rat) ca. 9000 mg/kg (solvent), 1350 mg/kg (Ferrocene)
- LC50: -
- Primary irritant effects: no
- Sensitization effects: no
- Additional information: skin contact over a long time leads to irritation. Low toxicity at swallowing, inhaling and absorption through the skin.
12. ECOLOGICAL INFORMATION
information about elimination (persistence and degradability)
general notes:
water hazard class (german) class: 2 (self classification), hazardous for water.
Do not allow preparation to reach ground water, water bodies and sewage systems. Preparation contains no AOX.
13. DISPOSAL CONSIDERATIONS
preparation:
- recommendation: Must not be disposed of together with household garbage.
- recommendation: See national regulations for waste.
- un-cleaned packaging:
- recommendation: special waste
14. TRANSPORT INFORMATION
UN-no: 1294
ADR and RID (domestic and cross border)
Class: 2 cipher: F1 Kemlernumber: 90 lable: 9
Name of good: 1294 Environmentally hazardous substance,
liquid, n.o.s. (C3-C9-alkylbenzenes)
Additional information:
IMDG:
Class: 2, IMDG-code: F1
EMS-No MFAG, Marine pollutant yes() no ()
technical name: Environmentally hazardous substance, liquid, N.O.S.
Label: 2
Additional information: -
Airtransport IATA-DGR and ICAO-TI
Class: 2 ID-Nr (if different from UN-No)
Technical name: Environmentally hazardous substance, liquid, N.O.S. packaging instructions
Label: 2
15. REGULATORY INFORMATION
designation according to EU guidelines:
- symbol: Xn
- hazardous designation: harmful
- contains: Toluene > 90%
- R-phrases: 11, harmful, may cause lung damage
- S-phrases 24 Avoid contact with skin, 64
If swallowed do not induce vomiting, seek medical advice immediately and show this container or label.
national regulations.
VbF (german) AIII
additional information: The information of this data sheet is in accordance to the point of technics today. It describes the product in view of safety requirements and is no quality specification.