hfa-4114 (CFPP improvers)
® WRT bvMATERIAL SAFETY DATASHEET
Revision: 2
Revision date: January, 2004
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
- Trade name: HFA 4114
- Use of the substance/preparation:
- Industry sector: Oilfield / Refinery
- Type of use: CFPP improver, additive for downstream products
2. COMPOSITION/ INFORMATION ON INGREDIENTS
chemical characterization:
- Polymer preparation in high boiling hydrocarbon solvents.
Hazardous ingredients:
- Kerosene (petroleum) Strait-run-kerosine
- Concentration: 50 - 55 %
- Cas-number 8008-20-6
- Einecs number: 232-366-4
- Hazard symbols Xn
- R-phrases: 65
3. HAZARDS IDENTIFICATION
No particular hazards known.
4. FIRST AID MEASURES
- General information: Remove soiled or soaked clothing immediately.
- On skin: Remove contaminated clothing immediately and drench affected skin with plenty of water. Then wash with soap and water. Contaminated clothing should be laundered before re-use.
- In eyes: If substance has got into eyes rinse thoroughly with plenty of water and seek medical advice.
- After ingestion: When swallowed seek medical aid immediately and show the physician the packaging or the label of the packaging.
- Inhalation: When spray fog inhaled, seek medical aid.
5. FIRE FIGHTING MEASURES
- Extinguishing media: Use water spray jet, foam, carbon dioxide, dry chemical (S43). Do not use strong water jet. Special hazards from the substance itself, its combustion products or from its vapours. In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO).
- Protective Clothing: Wear self-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
- Personal precaution: Ensure adequate ventilation. Shut off all ignition sources. Wear appropriate protective equipment.
- Environmental Precautions: Avoid runoff into storm sewers and ditches which lead to water-ways.
- Cleaning up: Dike and absorb spill with absorbent materials (eg sand, kieselguhr, universal binder). Take up dry - forms slippery surface with water.
7. HANDLING AND STORAGE
- Advice on safe handling: The shipping in Road tanker, railway wagon, or bulk container is normally at temperatures up to 80ºC, that is usually above the flash point. Provide good ventilation at the working area (local exhaust ventilation if necessary). Avoid formation of aerosols.
- Advice on protection against fire and explosion: Take precautions against accumulation of electrostatic charge. Keep away from sources of ignition - refrain from smoking. Vapours can form an explosive mixture with air.
- Further information on storage conditions: Keep container tightly closed in a well ventilated place
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
- General protective measures: Do not inhale vapours. Avoid contact with skin. Avoid contact with eyes. If the product is dispatched in a heated condition - take care for danger of scalding.
- Hygiene measures: Wash soiled clothing immediately
- Respiratory protection: Use respiratory protection in case of
- insufficient exhaust ventilation or prolonged exposure.
- Hand protection: Gloves (oil-resistant)
- Eye protection: Safety glasses
- Body protection: Protective clothing
9. PHYSICAL AND CHEMICAL PROPERTIES
- Appearance: liquid, viscous
- Colour: off white/transparent
- Odour: Aromatic
- Pour point: - 3ºC Method DIN/ISO 3016
- Starts to boil: 180°C (1.013 mbar) Method DIN 51751
- Flash point: approx 60°C Method EN 22719
- Ignition temp: approx 240ºC Method DIN 51794
- Lower explosion limit: 0,5 % (V) Method DIN 51649
- Upper explosion limit: 5% (V) Method 51649
- Vapour pressure: approx 1,6 mbar (20ºC) Method DIN 51754
- Density (40ºC): 0,9085 - 0,9105 gr/cm3 Method DIN 51757
- Solubility in water: insoluble (20ºC)
- Solubility/qualitative: soluble in hydrocarbons
- Viscosity (dynamic): 230mPas (40ºC) Method DIN 51562
- Viscosity (kinematic): approx 295 mm2/s (40ºC) Method DIN 51562
10. STABILITY AND REACTIVITY
- Thermal decomposition: No decomposition if used as prescribed.
- Hazardous reactions: Un-cleaned empty vessels may contain product gases which can form explosive mixtures with air.
- >200ºC LIBERATION OF ACETIC ACID.
11. TOXICOLOGICAL INFORMATION
Remarks: Toxicological data are not available. The product was classified on the basis of the calculation procedure of the preparations directive (88/379/EC)
12. ECOLOGICAL INFORMATION
- Biodegradability: approx 20 % (28 d) Method OECD 301 B
- Bacteria toxicity: EC50> 12g/l (activated sludge) Method OECD 209
- Remarks: By analogy with a product of similar composition.
13. DISPOSAL CONSIDERATIONS
Product in accordance with authority regulations, take to special waste incineration plant.
14. TRANSPORT INFORMATION
| ADR: | 3,III UN-number 1993 Hazard no: 30 Kerosene |
| RID: | 3,III UN-number 1993 Hazard no: 30 Kerosene |
| ADNR: | 3,III UN-number 1993 Hazard no: 30 Kerosene |
| IMDG: | 3 / III UN-number 1993 Kerosene |
| IATA: | 3 / III UN-number 1993 Kerosene |
| IMDG: | EmS: 3-07 |
| ADR: | Solution |
| RID: | Solution |
| ADNR: | Solution |
| IMDG: | Solution |
| IATA: | Solution |
15. REGULATORY INFORMATION
Labelling in accordance with EC-Directives. The product does not require a hazard warning label in accordance with EC Directives.
16. OTHER INFORMATION
Text of the R-phrases which are allocated to the ingredients/components mentioned in section 2 of this Safety Data Sheet.
65 Harmful; may cause lung damage if swallowed.
This information is based on our present state of knowledge. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application.